Oxidation of mephenesin and guaifenesin with chloramine-B in hydrochloric acid medium: Design of kinetic model

Kinetic, mechanistic and thermodynamic investigations on Iridium (III) catalyzed oxidation of D-Mannitol by N-chloro-p-toluenesulfonamide in perchloric acid medium

The present paper deals with the kinetics and mechanism of homogeneously Ir(III) chloride catalyzed oxidation of D-mannitol by chloramine-T [CAT] in perchloric acid medium in the temperature range of 30 to 45 0C. The reaction is carried out in the presence of mercuric acetate as a scavenger for chloride ion. The experimental results show first order kinetics with respect to the oxidant [CAT] an...

Kinetics and Mechanism of Oxidation of Vitamin B1 with Chloramine-b in Presence of Ruthenium (iii) Catalyst in Hydrochloric Acid Medium

Kinetic analysis of total Lead from spent Car battery by hydrochloric acid leaching

A study of the kinetic analysis of total lead from spent Car battery ash by hydrochloric acidleaching has been examined. The physico-chemical analysis of the ash powder was carried outby the Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) and X–ray diffraction (XRD).The effects of the acid concentration, temperature and particle size on the rate of battery ashdissolution have been investi...

Titrimetric And Spectrophotometric Determination Of Salbutamol Sulphate In Pharmaceuticals Using Chloramine-T And Two Dyes

Four new methods are described for the assay of salbutamol sulphate(SBS) in bulk drug and in dosage forms using chloramine-T and two dyes, methyl orange and indigocarmine, as reagents. In direct titrimetry (method A), aqueous solution of SBS is titrated with chloramine-T(CAT) in hydrochloric acid medium and in the presence of excess of potassium bromide, using methyl orange indicator. Back titr...

Optimization and kinetic evaluation of acid blue 193 degradation by UV/peroxydisulfate oxidation using response surface methodology

The optimization of process conditions for the degradation of Acid Blue 193 by UV/peroxydisulfate was investigated using response surface methodology (RSM). The effects of four parameters namely initial K2S2O8 concentration, UV irradiation, temperature, and initial dye concentration on two process responses, color removal and the rate constants of the first-order kinetic equations, were investi...